The importance of THINKING for a natural dyer

I am a natural dyer but I also enjoy reading about and cooking food. I was recently perusing Michael Ruhlman’s book, Twenty: 20 Techniques, 100 Recipes. The first chapter is titled “THINK: Where Cooking Begins”. The author talks about the importance of thinking to the cook.  I might say the same thing about the dye kitchen. Dyeing is not just about following a recipe, but thinking about and understanding the role of each of the ingredients.

Ruhlman recognizes that his list of techniques includes many that are also ingredients: salt, acid, sugar… One might say the same thing about our dye ingredients: mordant, acid,  base, or dye plant…  Awareness of what each ingredient contributes to the process is key to understanding how it fits into the larger picture of dyeing.

Let’s talk about mordants – alum specifically.

The alum we typically use in the dye studio is potassium aluminum sulfate [KAl(SO4)]. It is most likely made in a laboratory, is in powder or small crystal form, dissolves easily, and contains no contaminants such as iron.

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Alum (potassium aluminum sulfate) in powder form

Aluminum sulfate [Al2(SO4)3] is made by a different process and may be contaminated with small amounts or iron.  The first dyeing I ever did utilized naturally occurring alum gathered from the ground surface – no telling how impure or contaminated it was.

We often shorten the name of our mordant to simply  “alum” but there are many different types of alum and it may be best to use (and specify) potassium aluminum sulfate. I never purchase from a supplier who cannot provide material with that specific name.

Potassium aluminum sulfate bonds with the dyestuff and makes an insoluble lake INSIDE the fiber. Without this insoluble bond, the dye can wash out. This is why we don’t put dye, alum, and fiber in the same pot; inevitably some of the dye will bind with the alum in the bath OUTSIDE the fiber. That would be a waste of our dye and mordant.

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Alum and dye in the same bath to make a lake. The dye has bonded with the alum and become an insoluble pigment.

The traditional  approach to mordanting and dyeing is broken down into two steps.  1.) The alum is applied to the fiber. 2.) The fiber is dyed in a second bath, attaching the dye to the mordant and making the lake inside the fiber.

It’s important to get the mordant INSIDE the fiber. That is why we pre-wet and heat wool so that the scales will open up and the mordant goes inside. Otherwise we have ring dyeing, with the mordant and dye just sitting on the surface.

I have lately learned to dye silk using the Japanese approach of “middle mordanting” with Dr. Kazuki Yamazaki. The fiber is first dyed, then mordanted, and then re-immersed in the dye. This approach didn’t make a lot of sense to me until I experienced it and observed that it accomplished the same thing as pre-mordanting. The dye and mordant still go into the fiber and make the insoluble lake there. It’s a slower, quieter process which has the potential of building up layers of mordant and dye on the silk. This process is not suitable for wool.

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Sappanwood (Caesalpinia sappan) on silk: the first dyeing before the “middle mordanting”
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Sappanwood (Caesalpinia sappan) on silk yarn after the “middle mordanting” and subsequent dyeing

Some things to THINK about:

  • Alum is acidic – a useful thing to remember.
  • Once a fiber is mordanted, it is always mordanted. The mordanted fiber can be dried and stored indefinitely.
  • The more dye there is, the more mordant is needed.
  • Alum can be removed with a stronger acid, such as citric acid.
  • I typically use my alum at 15% of the fiber weight but I always test a new source of mordant in order to be sure that the strength is the same. Test by mordanting, dyeing, and observing.
  • Potassium aluminum sulfate is an excellent mordant for protein fibers.  I would take a different approach to mordanting cellulose.
  • When a dye lake is made OUTSIDE the fiber it results in an insoluble pigment.
  • When a dye lake is made INSIDE the fiber it results in an insoluble pigment.
  • How the mordant and dye are applied to the fiber is very important.
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Comparison of “middle mordant” and “pre-mordant” on silk. Weld (Reseda luteola) dye.

Experiments and Results

I am a weaver of textiles and a dyer. In the past I have used all types of chemical dyes to obtain desired results with my woven shibori fabrics. I live and work in the mountains of North Carolina near a small creek that flows into a river full of native trout. Our water comes from a shallow well and we have a septic system.  I have developed an an increased awareness of potential chemical pollution of these water sources and systems and have been inspired to begin a study of natural dyeing.

For the last 8 years I have been engaged in a learning adventure about natural colorants which I have found deeply satisfying. I have been exposed to great teachers: Michel Garcia of France and Joy Boutrup of Denmark. They are both scientists, and dyers, who have both helped me find a path which includes questioning and observing. Michel Garcia once stated in a class that it was more important to understand “why” than “how”. I have thought about this a great deal and always try to go beyond a recipe in order to understand the logic behind it.

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I am an artist, not a scientist,  but have developed the skills to observe carefully and trust my own experiments. If I don’t know whether “X”  or “Y” process will work best, I do them both and record the results. My goal, as an artist, is to learn effective processes. I don’t always have a definitive scientific answer but I have learned to  observe objectively and be willing to change the way I work.

Each experiment brings a new insight and the realization of just how complex the field of natural dye is. My understanding of the fibers and interactions with dyes themselves has deepened, and I have a new respect for botany and chemistry.

I regularly carry out lightfastness tests, using the blue wool scale, an international standard to measure  the lightfastness of dyes. As a result of the tests, I have relegated some dyes to the back of my shelves some dyes from my shelf because they don’t perform well enough. When I go back and read old dye books, history usually confirms what I learned first hand.

My teaching and my work is now done entirely with natural dyes. Frequently students and colleagues contact me with questions, requesting further clarification of process, or needing encouragement. I try to answer those questions and at this point have decided to answer them in a more public format in the hope that the information might be of use to others. Hence the creation of this blog: Natural Dyes: Experiments and Results.

I don’t always have definitive answers. I know only what I have experienced and that knowledge is constantly evolving. I trust and depend on my teachers and colleagues who are using natural dyes and we have begun to study and question together. So I will share some of my own lessons from my own dye studio, my “kitchen of natural colors”, as we all learn together.

Your feedback is welcome and desired.

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Lightfast test “working” in the window